*****UPDATE*****************
OK so Microsoft launched the "StartScreen" in PowerAPPs. The below instructions do not work anymore.
Click here for updated instructions.
There's some documentation on this that has the wrong syntax using a "?" but the correct operator is "&". At least in my system....
The correct syntax for the url is:
https://apps.powerapps.com/play/52e8bcfb-4fd6-41f1-bc1a-971a2fc7a555?ten...&ScreenName=1
Find this part of the URL in your Apps details > https://apps.powerapps.com/play/52e8bcfb-4fd6-41f1-bc1a-971a2fc7a555?ten...
Then add the parameter to the end on the url " &ScreenName=1 "
Add the following to your App's OnStart variable
" If(Param("ScreenName") = "1",Navigate(YourScreenName),Navigate(HomeScreen)) "
If the parameter "Screen=1" doesn't exist in the URL then the app will direct the user to the "HomeScreen" :)
In my case, when the app creates a new record, the platform send an email to the IT department letting the know a New Employee has started and need Network Permissions. The email notification sent has a link to a screen where IT can see all the New Hires that need account set - up. :)